FOM-03010
Water soluble monomer



Plastics manufacturing
Photocurable
FOM-03010 is a Fujifilm's unique novel monomer containing a betaine structure and a methacrylamide group that exhibits high hydrophilicity. It is highly hydrophilic and biocompatible as well as stable.

Chemical name | [3-(Methacryloylamino)propyl]dimethyl(3-sulfobutyl)ammonium hydroxide inner salt |
---|---|
CAS RN® | 83623-32-9 |
Physical characteristics
FOM-03010 | ||
---|---|---|
Physical characteristics | Form | Powder |
Color | White | |
Odor | Odorless |
|
Melting point | None |
Related laws and regulations
TSCA | Not Listed |
---|---|
EINECS | Not Listed |
REACH | Not Listed |
Characteristics
1) Highly water soluble and hydrophilic
- FOM-03010 dissolves in water at 50 wt% or more. It is easily soluble in solvents such as methanol and ethanol.
- Due to the betaine structure, it exhibits very high hydrophilicity. (CLogP = -10)

Many of the hydrophilic monomers currently on the market have CLogP values of around -2 to +1, which is an index of hydrophilicity/hydrophobicity.
FOM-03010 has a CLogP value of -10 and much higher hydrophilicity than these general-purpose monomers.

Also in the LogD value, which is a hydrophilicity index considering the dissociation of molecules under different pH environments, FOM-03010 shows high hydrophilicity with LogD = -4 (pH = 7).
MPC:2-Methacryloyloxyethyl phosphorylcholine
GLBT:Carboxymethyl betaine monomer
HEMA:2-Hydroxyethyl methacrylate
Solubility in various solvents and monomers
Solvent/monomer name | Solubility at each solid content concentration (weight%) | |||||||
---|---|---|---|---|---|---|---|---|
0.1 | 0.5 | 1 | 10 | 20 | 30 | 40 | 50 | |
Water | ◯ | ◯ | ◯ | ◯ | ◯ | ◯ | ◯ | ◯ |
Methanol | ◯ | ◯ | ◯ | ◯ | ◯ | ◯ | × | - |
Ethanol | ◯ | ◯ | ◯ | ◯ | × | - | - | - |
Isopropyl alcohol | ◯ | ◯ | × | - | - | - | - | - |
Dimethylsulfoxide | ◯ | ◯ | ◯ | ◯ | ◯ | × | - | - |
Acetone | × | - | - | - | - | - | - | - |
Ethyl acetate | × | - | - | - | - | - | - | - |
Dimethylacetamide | × | - | - | - | - | - | - | - |
2-Hydroxyethyl methacrylate (HEMA) |
◯ | ◯ | ◯ | ◯ | × | - | - | - |
N-(2-Hydroxyethyl) acrylamide | ◯ | ◯ | ◯ | ◯ | ◯ | × | - | - |
N,N-Dimethylacrylamide | ◯ | × | - | - | - | - | - | - |
4-Acryloyl morpholine | ◯ | × | - | - | - | - | - | - |
※Measured at liquid temperature of 25°C
※ 🞅: Soluble 🞨: Insoluble -: Not measured
2) Excellent in hydrolysis resistance
- Excellent in hydrolytic resistance in acidic to basic aqueous solutions.
3) Highly biocompatible
- Resistant to cell adhesion and platelet adhesion. *Based on the test by FUJIFILM
Verification of the inhibitory effect of cell adhesion

Applications
Imparting biocompatibility to various products
Examples:Medical devices, materials for analytical instruments, materials for bioengineering
Hydrophilic/antifouling coating
Examples:Separating film, analytical instruments, building materials, water-absorbing materials, fibers, household products, cleaning agents
Water retaining/moisturizing materials
Examples:Additives for cosmetics and toiletry products, civil engineering materials, sanitary goods
Control of hydrophilicity/hydrophobicity of various cured components
Examples:Paint, coating, kneaded and molded products, printing materials, gel, drug formulation materials
Usage example
- A functional coat with a high hydrophilicity can be formed.
- Due to the high water solubility of the monomer and initiator, a coat solution can be prepared using water as a solvent.

Example of composition of Coat A
Name of raw material | Compounding ratio (wt%) |
Water soluble crosslinking agent (FOM-03006) | 30 |
---|---|
Water soluble monomer (FOM-03010) | 67 |
Water soluble light radical initiator (FOM-03011) | 3 |
Methanol | 400 |
Usage example and physical characteristics of Coat A
- Apply to PET substrate, dry (50°C/5 min), and then photocure (3 J/cm2)
※Lamp used: High pressure mercury lamp (Exposure is controlled as UV-A)
Coats evaluated | Water contact angle (°) |
PET alone | 75 |
---|---|
Coat A | 35 |
Impregnate Coat A with water and dry | 44 |
In evaluation of wettability by water contact angle showing affinity with water, Coat A exhibits high hydrophilicity with a low contact angle, and maintains the hydrophilicity even when it is re-dried after being impregnated with water.
Contact us for more details.
We are waiting for questions and requests on products.